Brad Pitt and Angelina Jolie Through the Years

News broke Tuesday that Brad Pitt and Angelina Jolie are separating after more than 10 years together. Pictured here in 2005's Mr. and Mrs. Smith, the two actors started dating soon after they met on the set, following the dissolution of Pitt's five-year marriage to Jennifer Aniston. Pitt and Jolie went on to parent six children together, and finally tied the knot in August 2014. They reteamed on the big screen late last year, appearing together in By the Sea, which Jolie also directed. TMZ reported Tuesday that Jolie filed for divorce from Pitt this week, citing irreconcilable differences, and asking for physical custody of Maddox, Pax, Zahara, Shiloh, Vivienne, and Knox. See photos of the two through the years, ahead.