Brad Pitt and Angelina Jolie Through the Years
By Madeline Boardman Updated September 20, 2016 at 10:47 PM EDT
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Brad Pitt and Angelina Jolie
Brad Pitt and Angelina Jolie
Credit: Stephen Vaughn
News broke Tuesday that Brad Pitt and Angelina Jolie are separating after more than 10 years together. Pictured here in 2005's Mr. and Mrs. Smith, the two actors started dating soon after they met on the set, following the dissolution of Pitt's five-year marriage to Jennifer Aniston. Pitt and Jolie went on to parent six children together, and finally tied the knot in August 2014. They reteamed on the big screen late last year, appearing together in By the Sea, which Jolie also directed. TMZ reported Tuesday that Jolie filed for divorce from Pitt this week, citing irreconcilable differences, and asking for physical custody of Maddox, Pax, Zahara, Shiloh, Vivienne, and Knox. See photos of the two through the years, ahead.
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Angelina Jolie and Brad Pitt at the Paris Hotel in Las Vegas on March 17, 2005
Angelina Jolie and Brad Pitt at the Paris Hotel in Las Vegas on March 17, 2005
Credit: Gregg DeGuire/WireImage
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Brad Pitt, Arnon Milchan, and Angelina Jolie in Los Angeles on June 7, 2005
Brad Pitt, Arnon Milchan, and Angelina Jolie in Los Angeles on June 7, 2005
Credit: Lester Cohen/WireImage
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Angelina Jolie, Brad Pitt, and Shiloh on the Cover of PEOPLE in June 2006
Brad Pitt, Angelina Jolie | Joining A-list hyphenate sibs Maddox and Zahara, Shiloh Jolie-Pitt was born in Namibia amid a paparazzi craze. People scored the exclusive shots of the family,Â…
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Angelina Jolie, Zahara, Brad Pitt, and Maddox in Mumbai on November 12, 2006
Angelina Jolie, Zahara, Brad Pitt, and Maddox in Mumbai on November 12, 2006
Credit: STR/AFP/Getty Images
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Angelina Jolie and Brad Pitt at the Premiere of God Grew Tired of Us in West Hollywood, Calif. on January 8, 2007
Angelina Jolie and Brad Pitt at the Premiere of God Grew Tired of Us in West Hollywood, Calif. on January 8, 2007
Credit: Kevin Winter/Getty Images
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Angelina Jolie and Brad Pitt at the Premiere of Ocean's 13 in Hollywood on June 5, 2007
Angelina Jolie and Brad Pitt at the Premiere of Ocean's 13 in Hollywood on June 5, 2007
Credit: Kevin Winter/Getty Images
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Angelina Jolie and Brad Pitt at the 14th Annual Screen Actors Guild Awards in Los Angeles on January 27, 2008
Angelina Jolie and Brad Pitt at the 14th Annual Screen Actors Guild Awards in Los Angeles on January 27, 2008
Credit: Lester Cohen/WireImage
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Brad Pitt and Angelina Jolie at the Kung Fu Panda Premiere at the 61st Cannes International Film Festival on May 15 , 2008
Brad Pitt and Angelina Jolie at the Kung Fu Panda Premiere at the 61st Cannes International Film Festival on May 15 , 2008
Credit: Pascal Le Segretain/Getty Images
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Brad Pitt and Angelina Jolie at the 81st Academy Awards on February 22, 2009
Brad Pitt and Angelina Jolie at the 81st Academy Awards on February 22, 2009
Credit: Robyn Beck/AFP/Getty Images
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Brad Pitt, Angelina Jolie, and Maddox at the Premiere of Invictus in Beverly Hills on December 3, 2009
Brad Pitt, Angelina Jolie, and Maddox at the Premiere of Invictus in Beverly Hills on December 3, 2009
Credit: Kevin Winter/Getty Images
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Angelina Jolie and Brad Pitt at The Tree Of Life Premiere at the 64th Annual Cannes Film Festival on May 16, 2011
Angelina Jolie and Brad Pitt at The Tree Of Life Premiere at the 64th Annual Cannes Film Festival on May 16, 2011
Credit: Andreas Rentz/Getty Images
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Angelina Jolie and Brad Pitt at the Cinema for Peace Gala at the 62nd Berlin International Film Festival on February 13, 2012
Angelina Jolie and Brad Pitt at the Cinema for Peace Gala at the 62nd Berlin International Film Festival on February 13, 2012
Credit: Pascal Le Segretain/Getty Images
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Brad Pitt and Angelina Jolie at the 84th Annual Academy Awards on February 26, 2012
Brad Pitt and Angelina Jolie at the 84th Annual Academy Awards on February 26, 2012
Credit: Jason Merritt/Getty Images
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Maddox, Angelina Jolie, and Brad Pitt at the 2013 Governors Awards in Los Angeles on November 16, 2013
Maddox, Angelina Jolie, and Brad Pitt at the 2013 Governors Awards in Los Angeles on November 16, 2013
Credit: John Shearer/Invision/AP
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Angelina Jolie and Brad Pitt at the World Premiere of Maleficent in Hollywood on May 28, 2014
Angelina Jolie and Brad Pitt at the World Premiere of Maleficent in Hollywood on May 28, 2014
Credit: Kevin Winter/Getty Images
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Angelina Jolie and Brad Pitt at the Global Summit to End Sexual Violence in Conflict in London on June 13, 2014
Angelina Jolie and Brad Pitt at the Global Summit to End Sexual Violence in Conflict in London on June 13, 2014
Credit: Karwai Tang/WireImage
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Brad Pitt, Pax, Shiloh, and Maddox at the Premiere of Unbroken on December 15, 2014
Brad Pitt, Pax, Shiloh, and Maddox at the Premiere of Unbroken on December 15, 2014
Credit: Robyn Beck/AFP/Getty Images
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Angelina Jolie and Brad Pitt at the 15th Annual AFI Awards Luncheon in Beverly Hills on January 9, 2015
Angelina Jolie and Brad Pitt at the 15th Annual AFI Awards Luncheon in Beverly Hills on January 9, 2015
Credit: Michael Kovac/Getty Images
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Brad Pitt and Angelina Jolie in By the Sea in 2015
Brad Pitt and Angelina Jolie in By the Sea in 2015
Credit: Universal Pictures
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Angelina Jolie and Brad Pitt at an Academy Screening of By the Sea in New York City on November 3, 2015
Angelina Jolie and Brad Pitt at an Academy Screening of By the Sea in New York City on November 3, 2015
Credit: Robin Marchant/Getty Images
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Angelina Jolie and Brad Pitt at AFI Fest 2015 on November 5, 2015
Angelina Jolie and Brad Pitt at AFI Fest 2015 on November 5, 2015
Credit: Jason Merritt/Getty Images
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