By Andrea Towers
Updated March 21, 2014 at 05:00 PM EDT

Black Widow and Punisher are on a mission to save the world in their first feature-length film — and we’ve got a first look at what you can expect from their exploits.

According to the official synopsis, Marvel’s Avengers Confidential: Black Widow and Punisher finds Natasha Romanoff’s Black Widow (voiced by Dexter’s Jennifer Carpenter) and Frank Castle’s The Punisher (Call of Duty: Modern Warfare 3‘s Brian Bloom) joining forces to stop a terrorist organization called Leviathan, which plans to sell stolen S.H.I.E.L.D. technology. They’ll work alongside fellow Avengers Thor, Iron Man and Hulk — but with two intense supers, both of whom are used to doing things “their way,” whose leadership will prevail?

Check out the exclusive clip for more.

Avengers Confidential: Black Widow and Punisher arrives on DVD, Blu-Ray and digital March 25.