By Ray Rahman
Updated August 06, 2013 at 01:45 PM EDT
Anna Webber

After a long absence, Gov’t Mule is gearing up to release their first studio collection in four years next month. Titled Shout!, it’ll be a double-disc set, with the first half containing 11 new songs and the second half featuring special guest vocalists like Elvis Costello, Ben Harper, and Dave Matthews teaming up with the band to reinterpret those songs.

Among them is My Morning Jacket frontman, hair wonder, and sometime solo artist Jim James, who collabs with Gov’t Mule on “Captured” — and you can hear it exclusively here.

Give the song a listen below:

You can preorder Shout!, out Sept. 24, here and catch Gov’t Mule live at tour dates below:

8/17 Scranton, PA @ Peach Festival

9/5 Arrington, VA @ Interlocken Festival (w/ Gov’t Mule AND The Warren Haynes Band in one day)

9/13 Fredericton, NB @ Harvest Jazz & Blues Festival

9/14 Hampton Beach, NH @ Hampton Beach Casino Ballroom

9/15 Burlington, VT @ Grand Point North Festival

9/17 New York, NY @ Best Buy Theater

9/18 Pittsburgh, PA @ Stage AE

9/19 Detroit, MI @ Fillmore Detroit

9/20 Cleveland, OH @ House of Blues Cleveland

9/21 Northampton, MA @ Calvin Theatre & Performing Arts Center

9/26 Atlanta, GA @ The Tabernacle

9/27 Louisville, KY @ Brown Theatre

9/28 Nashville, TN @ Ryman Auditorium

10/1 Indianapolis, IN @ Murat Theater

10/2 Columbus, OH @ LC Pavilion (indoor)

10/4 Chicago, IL @ Vic Theatre

10/5 Chicago, IL @ Vic Theatre