Ross and Rachel. Carrie and Big. Clair and Cliff. Ricky and Lucy. These are just a few of the iconic pairings competing for the chance to be EW's "Greatest TV Couple of All Time." Vote in the polls below to determine who will move on to the next round. Now for the 16 couples in our "Pick Me, Choose Me, Love Me" conference.

Damon and Elena, The Vampire Diaries vs. Niles and Daphne, Frasier

Dr. Ross and Carol, ER vs. Felicity and Ben, Felicity

Willow and Tara, Buffy the Vampire Slayer vs. Booth and Bones, Bones

Dan and Roseanne, Roseanne vs. Buffy and Spike, Buffy the Vampire Slayer

Carrie and Big, Sex and the City vs. Kurt and Blaine, Glee

David and Maddie, Moonlighting vs. Leonard and Penny, The Big Bang Theory

Chuck and Blair, Gossip Girl vs. Apollo and Starbuck, Battlestar Galactica

Matthew and Mary, Downton Abbey vs. Peter and Olivia, Fringe

Just catching up? See more first-round relationships from the "Baby, You're the Greatest" conference.

The Greatest TV Romances:

Episode Recaps

Battlestar Galactica
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