By Sandra Gonzalez
Updated August 17, 2011 at 12:00 PM EDT
Mark Sullivan/

Forgive me. Are these tears in my eyes? Indeed, they are, but they come only from the pure joy as CW confirms to EW that two Buffy alums — Charisma Carpenter and James Marsters — will be guesting in the fifth episode of Supernatural this season. But who will they play?

Husband and wife… with a twist!

Marsters will play a man whose scorned wife (Carpenter), who is also a witch, is taking her anger out on the entire town in the episode, titled “Shut Up, Dr. Phil,” according to TV Line.

This will mark the first time Carpenter, best known for her run as Cordelia on the former WB show, and Marsters, who played Spike, have shared a scene together since their days on Buffy the Vampire Slayer spin-off, Angel.

Supernatural returns for it’s seventh season Sept. 23.

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