By Lynette Rice
May 19, 2010 at 09:54 PM EDT

Image Credit: Danny Moloshok/LandovNightline scored the first interview with Jesse James since the break-up of his marriage to actress Sandra Bullock. In the installment airing Tuesday May 25, James talks to Vicki Mabrey about the split and why he went to rehab. He’s also expected to address the role he’ll play in the raising of Louis, the baby boy Bullock recently adopted. James issued a public apology after Bullock spoke to People.