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Exclusive: 'Chuck' braces for attack of Olivia Munn

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olivia-munn-chuckImage Credit: Frederick M. Brown/Getty Images; Trae Patton/NBCActress–author–model–animal crusader–Daily Show correspondent Olivia Munn can now add superspy to her endless list of hyphenations when she guest-stars on Chuck this fall!

Munn, who has a regular role on NBC’s midseason comedy Perfect Couples, will play an impossibly cool, smart, and pretty CIA agent who intimidates and schools Chuck and Morgan in the season 4 premiere on Sept. 20. That just so happens to be the same episode that features a guest turn by iconic Rocky IV villain Dolph Lundgren.

In other Chuck casting news, the show is looking for a real-life supermodel to play a dangerous, sexy, and kick-ass supermodel in this season’s second episode, titled “Chuck vs. the Suitcase.” Got casting tips? Post ’em below! And while you’re at it, share your thoughts on Munn on Chuck!

TV scoop is best served instantaneously, so follow me on Twitter via @michaelausiello