July 20, 2010 at 07:46 PM EDT

Image Credit: Frederick M. Brown/Getty Images; Trae Patton/NBCActress–author–model–animal crusader–Daily Show correspondent Olivia Munn can now add superspy to her endless list of hyphenations when she guest-stars on Chuck this fall!

Munn, who has a regular role on NBC’s midseason comedy Perfect Couples, will play an impossibly cool, smart, and pretty CIA agent who intimidates and schools Chuck and Morgan in the season 4 premiere on Sept. 20. That just so happens to be the same episode that features a guest turn by iconic Rocky IV villain Dolph Lundgren.

In other Chuck casting news, the show is looking for a real-life supermodel to play a dangerous, sexy, and kick-ass supermodel in this season’s second episode, titled “Chuck vs. the Suitcase.” Got casting tips? Post ’em below! And while you’re at it, share your thoughts on Munn on Chuck!

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